A robust supramolecular synthon: effect on melting points and Wallach's rule
نویسندگان
چکیده
منابع مشابه
1,1,2,2-Tetracyanocyclopropane (TCCP) as supramolecular synthon.
The 1,1,2,2-tetracyanocyclopropane (TCCP) unit presents a synthetically accessible and versatile synthon that can interact with lone-pair or π-electrons by 'non-covalent carbon bonding'. Complexes of TCCP with common small molecules, anions, aromatics like fullerenes, amino acids and nucleobases were computed at the DFT BP86-D3/def2-TZVP level of theory. Binding energies vary between about -10 ...
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15 صفحه اولIdentification of a new supramolecular synthon in o-anisaldehydes: molecular self-assembly into tapes and staircases
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2009
ISSN: 0108-7673
DOI: 10.1107/s0108767309098110